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Another strategy for obtaining alkyl lenalidomide derivatives is to convert the amino group of lenalidomide to an aryl boronic ester 88 , which then undergoes oxidative hydrolysis to give compound 89

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Notably, this emergent passive permeability may compromise the intended targeting specificity and safety profile, highlighting the need for future designs that limit intramolecular foldingfor example, through linker rigidification or shortening between the PSMA ligand and the disulfide, or by employing more rigid degraders